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You can create a Chrome theme to use on your browser. To do this you need to go to Chrome web store. Then search for themes and then go to My Chrome Themes. Click on Add then it will load an interface that allows you to upload an image from your computer and use it as your background.
Then adjust other settings such as placement and color. Then save and install the theme.
Start here http://my-chrome-theme.en.softonic.com/